Two ways out, one pair of nets

Four holes, two nets

The output end has two pairs of plated holes, and the pairs overlap into a figure-of-eight pad. That is easiest to see on a board with the terminal off:

The larger pair is 1.1 mm across and 3.5 mm apart — that is the screw terminal's footprint. The smaller pair is 1.0 mm across and 2.54 mm apart, which is the standard breadboard pitch. They are 1.798 mm apart along the board and joined by copper, so they are the same two connections offered twice, not two separate outputs.

You get one of them

The terminal block's body runs from roughly 19.0 mm to 25.5 mm along the board. The header holes are at 24.15 mm. So the terminal stands over the holes you would want to put pins in, and the choice is made for you unless you are willing to desolder a part that is already fitted.

For nearly everything, the terminal is the better end of that bargain: it takes bare wire up to about 1.5 mm², it needs no soldering, and it holds against a tug. The pins are worth the trouble only when the board has to plug into a breadboard alongside the rest of a circuit.

Or use neither

The holes do not need a connector in them. For a build that will be screwed into a box and left there, tin a length of wire and solder it straight through the terminal pair — 1.1 mm takes up to about 18 AWG comfortably, which is more copper than most of these boards will ever be asked to carry.

Whichever way the wire leaves, check the polarity before the charger goes in. VCC on this board can be 20 V, and there is nothing on it to stop a reversed connection reaching your circuit.